Mathematical Model for Isothermal Wire-Coating From a Bath of Giesekus Viscoelastic Fluid

A mathematical model of wire-coating based on Giesekus constitutive equation is analyzed under isothermal conditions. It is desired to see the functional dependence of Giesekus model parameters on the important operating variables in the wire-coating process, which include volumetric flow rate (later referred to as flow rate), shear stress at the wire surface (later referred to as shear stress), force required for pulling the wire (later referred to as force), and radius of the coated wire (later referred to as coated wire thickness). To this end, the equation governing the laminar, incompressible, and rectilinear flow is first derived and then solved analytically for the case of vanishing axial pressure gradient. A numerical procedure is described to obtain the solution for the case of nonvanishing pressure gradient. Our results indicate that the magnitude of shear stress and force follow a decreasing trend with increasing Giesekus model parameters in both cases. The flow rate and coated wire thickness decrease on increasing the Giesekus model parameters when there is no imposed pressure gradient. However, in the presence of pressure gradient these variables first decrease with increasing Giesekus model parameters and then follow an increasing trend.     

Data interpretation for spectral sensors with correlated bands

New classes of spectral sensors are emerging that have significant overlap in the band spectral response functions. While conventional sensors such as the Multispectral Thermal Images (MTI) or Landsat may have responses with a few percent overlap between adjacent bands, some of the emerging sensors can have more than 50% correlation among all spectral bands. The traditional geometrical models used to describe spectral data fail when such high levels of correlation exist. In this paper we present a generalized geometrical model that relies on functional analysis. We define a sensor space and a scene space that can be used to characterize the suitability of a sensor for a particular spectral sensing task. We demonstrate that classifiers based on first-order distance and angle metrics fail for sensors with highly correlated bands unless appropriate preprocessing is carried out. We further show that second-order statistical classifiers are largely immune to many of the problems introduced by the correlated band responses.     

Enzymolysis reaction kinetics and thermodynamics of rapeseed protein with sequential dual‐frequency ultrasound pretreatment

We evaluated the effect of sequential dual‐frequency ultrasound (SDFU) pretreatments on rapeseed protein enzymolysis, using alcalase as a model enzyme. Hydrolysed protein concentrations, enzymolysis kinetics and thermodynamic parameters were investigated. The results showed that the hydrolysed rapeseed protein concentration following SDFU pretreatments was higher compared to that of the control for up to 75 min of enzymolysis at various substrate concentrations of 5–25 g L^?1; both control and SDFU pretreatment groups showed first‐order reaction kinetics. Compared to the control, the Michaelis–Menten constant (K_M) value decreased remarkably by 17.61%, while an increase in the binding frequency between enzyme and substrate (K_A) by 10.47% was observed. The thermodynamic parameters, enthalpy, entropy and activation energy were reduced in the SDFU pretreatment group compared to the control by 31.78%, 18.0% and 29.56%, respectively. SDFU pretreatment showed little effect on Gibbs free energy at the various temperatures studied.     

Camptothecin in sterically stabilized phospholipid nano-micelles: a novel solvent pH change solubilization method

Camptothecin (CPT) is a topoisomerase I inhibitor that acts against a broad spectrum of cancers. Unfortunately clinical application of CPT is limited by insolubility, instability, and toxicity problems. To circumvent these delivery problems of CPT, we propose biocompatible, targeted sterically stabilized micelles (SSM) as nanocarriers for CPT (CPT-SSM). SSM composed of polyethylene glycol (PEGylated) phospholipids are attractive nanocarriers for CPT delivery because they are sufficiently small to extravasate through the leaky microvasculature of tumor and inflamed tissues for passive targeting. The purpose of this study was to develop a novel method of preparing CPT-SSM based on its pH dependent, reversible carboxylate-lactone conversion chemistry. CPT carboxylate was added to SSM at pH 5 that favored the formation of active but hydrophobic CPT lactone for spontaneous association with SSM. The kinetics of CPT conversion and CPT-SSM formation, and the effect of varying CPT-PEGylated phospholipid molar ratio on CPT-SSM properties and CPT solubilization were evaluated. CPT converted gradually from the carboxylate form to lactone, and CPT-SSM were formed after 12 h incubation. The mean size of CPT-SSM was approximately 14 nm. CPT solubilization (approximately 12 microg/ml) and other CPT-SSM micelle properties did not change significantly with increasing CPT to PEGylated hospholipid molar ratios using this novel method, unlike the coprecipitation/reconstitution technique previously reported. This reproducible CPT solubilization in SSM was attributed to avoidance of drug aggregate formation by this method. The advantages of our solvent pH change method to prepare CPT-SSM support further investigations of this approach to other hydrophobic drugs similar to CPT in chemistry and also CPT molecular solubilization in other nanocarriers.     

The bacterial quality of red meat and offal in Casablanca (Morocco)

The present study aimed to evaluate the bacteriological quality of beef (n = 52), lamb (n = 52) and beef offal (n = 52) marketed in Casablanca, Morocco. Meat and offal samples (n = 156), were collected randomly from butcheries, supermarkets, and slaughterhouses. Two sampling periods were considered, one during the hot season and the second one during the cold season. The samples were analyzed for the presence of the following bacteria: Escherichia coli, coagulase-positive Staphylococcus, Clostridium perfringens, Salmonella, and Listeria monocytogenes. Results indicated that counts of the aerobic plate count, and fecal coliforms were particularly high in all the samples analyzed. E. coli, coagulase-positive Staphylococcus and C. perfringens were detected in 37.8, 16, and 4.5% of the meat samples, respectively. Neither Salmonella nor L. monocytogenes were isolated from meat samples. Approximately 26.9% of beef, 34.6% of lamb and 28.8% of beef offal samples contained bacteria above the maximum limits established by the Moroccan regulatory standards for meat and meat products. Seasonality and the distribution location significantly (p < 0.05) affected bacterial populations: the hot season and butcheries appeared to be cases where the highest populations of bacteria in meat were observed. These high levels of microbiological contamination attest the poor hygienic quality of meat and offal, possibly due to uncontrolled processing, storage, and handling of these products.     

Steady flow of an Eyring Powell fluid over a moving surface with convective boundary conditions

In this article, the flow and heat transfer of Eyring Powell fluid over a continuously moving surface in the presence of a free stream velocity are investigated. Convective boundary conditions have been used in the problem formulation. The solution for velocity and temperature are computed by applying the homotopy analysis method (HAM). The effects of emerging fluid parameters (?), (δ) and Prandtl number (Pr) on the velocity and temperature are illustrated through graphs and tables for different values of λ. It is found that the boundary layer thickness is an increasing function of (?) and decreasing function of (δ). However the temperature and thermal boundary layer thickness decrease when the values of (?) and (δ) are increased.     

Influence of compliant walls on peristaltic motion with heat/mass transfer and chemical reaction

In this work the fundamental problem of peristalsis with heat and mass transfer is investigated in the presence of a chemical reaction. An incompressible viscous fluid is considered in a channel with compliant walls. Mathematical modeling is based upon the laws of mass, linear momentum, energy and concentration. Analysis is presented not only for long wavelength and low Reynolds number but also for small Grashof number. The solutions are carried out for the stream function, temperature, concentration field and heat transfer coefficient. The results of various interesting parameters are plotted and discussed.     

A study on heat transfer in a second‐grade fluid through a porous medium with the modified differential transform method

This study investigates the boundary‐layer flow and heat transfer characteristics in a second‐grade fluid through a porous medium. The similarity transformation for the governing equations gives a system of nonlinear ordinary differential equations which are analytically solved by the differential transform method (DTM) and the DTM‐Padé. The DTM‐Padé is a combination of the DTM and the Padé approximant. The convergence analysis elucidates that the DTM does not give accurate results for large values of independent variables. Hence the DTM is not applicable for the solution of boundary‐layer flow problems having boundary conditions at infinity. Comparison between the solutions obtained by the DTM and the DTM‐Padé with numerical solution (fourth‐order Runge–Kutta with shooting method) illustrates that the DTM‐Padé is the most effective method for solving the problems that have boundary conditions at infinity. © 2012 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library (wileyonlinelibrary.com/journal/htj). DOI 10.1002/htj.21030     

HALL EFFECTS ON UNSTEADY FLOW DUE TO NON-COAXIALLY ROTATING DISK AND A FLUID AT INFINITY

An investigation is made on the unsteady magnetohydrodynamic (MHD) flow caused by the non-coaxial rotation of a disk and a fluid at infinity being permeated by a transverse magnetic field. The disk is porous and nonconducting and executes oscillations in its own plane. The Laplace transform method is used to obtain the exact solution of the velocity field. The structure of the steady and unsteady flow fields is investigated. It is shown that the ultimate steady-state blowing solution is established in the presence of Hall current also for resonant frequency, which was not possible in the hydrodynamic case. The combined effects of Hall current, rotation, and suction or blowing are examined. The physical significance of mathematical results is given with various limiting cases.